10a Publications from my early career

From postdoctoral work at Imperial College and Universität des Saarlandes

Phosphide Delivery to a Cyclotrisilene T. P. Robinson, M. J. Cowley, D. Scheschkewitz*, and J. M. Goicoechea*, Angew. Chem. Int. Ed., 2015, 54, 683–86.

From Disilene (Si=Si) to Phosphasilene (Si=P) and Phosphacumulene (P=C=N) P. Willmes, M. J. Cowley, M. Hartmann, M. Zimmer, V. Huch, and D. Scheschkewitz*, Angew. Chem. Int. Ed., 2014, 53, 2216–20.

Donor–Acceptor Adducts of a 1, 3‐Disila‐2‐oxyallyl Zwitterion M. J. Cowley, V. Huch, and D. Scheschkewitz*, Chem. Eur. J., 2014, 20, 9221–24.

Carbonylation of Cyclotrisilenes M. J. Cowley, Y. Ohmori, V. Huch, M. Ichinohe, A. Sekiguchi, and D. Scheschkewitz*, Angew. Chem. Int. Ed., 2013, 52, 13247–50. (‘Very Important Paper’)

Equilibrium between a cyclotrisilene and an isolable base adduct of a disilenyl silylene M. J. Cowley, V. Huch, H. S. Rzepa, and D. Scheschkewitz*, Nature Chem., 2013, 5, 876–9.

Functionalized cyclic disilenes via ring expansion of cyclotrisilenes with isocyanides Y. Ohmori, M. Ichinohe, A. Sekiguchi, M. J. Cowley, V. Huch, and D. Scheschkewitz*, Organometallics, 2013, 32, 1591–4.

Reversible base coordination to a disilene K. Leszczyńska, K. Abersfelder, A. Mix, B. Neumann, H.-G. Stammler, M. J. Cowley, P. Jutzi, and D. Scheschkewitz*, Angew. Chem. Int. Ed., 2012, 51, 6785–8.

Transmetallation reactions of a lithium disilenide M. J. Cowley, K. Abersfelder, A. J. P. White, M. Majumdar, and D. Scheschkewitz*, Chem. Commun., 2012, 48, 6595–7.
From postdoctoral work at University of York

Probing signal amplification by reversible exchange using an NMR flow system R. E. Mewis, K. D. Atkinson, M. J. Cowley, S. B. Duckett*, G. G. R. Green,* R. A Green, L. R. Highton, D. Kilgour, L. S. Lloyd, J. a B. Lohman, and D. C. Williamson, Magn. Reson. Chem., 2014 doi: 10.1002/mrc.4073.

Hyperpolarisation through reversible interactions with para-hydrogen L. S. Lloyd, A. Asghar, M. J. Burns, A. Charlton, S. Coombes, M. J. Cowley, G. J. Dear, S. B. Duckett,* G. R. Genov, G. G. R. Green,* L. A. R. Highton, A. J. J. Hooper, M. Khan, I. G. Khazal, R. J. Lewis, R. E. Mewis, A. D. Roberts, A. J. Ruddlesden, Catal. Sci. Technol., 2014, 4, 3544–54.

Iridium N-heterocyclic carbene complexes as efficient catalysts for magnetization transfer from para-hydrogen M. J. Cowley, R. W. Adams, K. D. Atkinson, M. C. R. Cockett, S. B. Duckett*, G. G. R. Green*, J. a B. Lohman, R. Kerssebaum, D. Kilgour, and R. E. Mewis, J. Am. Chem. Soc., 2011, 133, 6134–7.

Reversible interactions with para-hydrogen enhance NMR sensitivity by polarization transfer R. W. Adams, J. A. Aguilar, K. D. Atkinson, M. J. Cowley, P. I. P. Elliott, S. B. Duckett*, G. G. R. Green,* I. G. Khazal, J. López-Serrano, and D. C. Williamson, Science, 2009, 323, 1708–11.

Spontaneous Transfer of Para hydrogen Derived Spin Order to Pyridine at Low Magnetic Field Kevin D Atkinson, M. J. Cowley, P. I. Elliott, S. B. Duckett*, G. G. R. Green*, J. López-Serrano, and A. C. Whitwood, J. Am. Chem. Soc., 2009, 131, 13362–8.

Para-hydrogen induced polarization without incorporation of para-hydrogen into the analyte D. Atkinson, M. J. Cowley, S. B. Duckett*, P. I. Elliott, G. G. Green*, J. López-Serrano, I. G. Khazal, and A. C. Whitwood, Inorg. Chem., 2008, 48, 663–70.

From my PhD at University of York

Rhodium vinylidene and alkyne complexes containing a pendant uracil group M. J. Cowley, J. M. Lynam*, and A. C. Whitwood, J. Organomet. Chem., 2010, 695, 18–25.

Ruthenium alkynyl, carbene and alkenyl complexes containing pendant uracil groups: an investigation into the formation of alkenyl-phosphonio complexes J. Cowley, J. M. Lynam*, R. S. Moneypenny, A. C. Whitwood, and A. J. Wilson, Dalton Trans., 2009, 9529–42.

A mechanistic study into the interconversion of rhodium alkyne, alkynyl hydride and vinylidene complexes Cowley, J. Lynam*, and J. Slattery, Dalton. Trans., 2008, 4552–4. (‘Hot paper’)

One-Electron Reduction of Molybdenum η2 (4e)-Alkyne Complexes as a Pathway to the η2 (3e) Vinyl Ligand S. Baines, M. Cowley, A. Chafen, and J. Lynam*, Organometallics, 2007, 26, 1093–5.

Transition metal vinylidene complexes as supramolecular building blocks: nucleobase-mediated self-assembly of crystals with hexagonal symmetry M. Cowley and J. Lynam*, Dalton. Trans., 2007, 4427–38.

© 2022 Michael Cowley