10a Publications from my early career
From postdoctoral work at Imperial College and Universität des Saarlandes
Phosphide Delivery to a Cyclotrisilene T. P. Robinson, M. J. Cowley, D. Scheschkewitz*, and J. M. Goicoechea*, Angew. Chem. Int. Ed., 2015, 54, 683–86.
From Disilene (Si=Si) to Phosphasilene (Si=P) and Phosphacumulene (P=C=N) P. Willmes, M. J. Cowley, M. Hartmann, M. Zimmer, V. Huch, and D. Scheschkewitz*, Angew. Chem. Int. Ed., 2014, 53, 2216–20.
Donor–Acceptor Adducts of a 1, 3‐Disila‐2‐oxyallyl Zwitterion M. J. Cowley, V. Huch, and D. Scheschkewitz*, Chem. Eur. J., 2014, 20, 9221–24.
Carbonylation of Cyclotrisilenes M. J. Cowley, Y. Ohmori, V. Huch, M. Ichinohe, A. Sekiguchi, and D. Scheschkewitz*, Angew. Chem. Int. Ed., 2013, 52, 13247–50. (‘Very Important Paper’)
Equilibrium between a cyclotrisilene and an isolable base adduct of a disilenyl silylene M. J. Cowley, V. Huch, H. S. Rzepa, and D. Scheschkewitz*, Nature Chem., 2013, 5, 876–9.
Functionalized cyclic disilenes via ring expansion of cyclotrisilenes with isocyanides Y. Ohmori, M. Ichinohe, A. Sekiguchi, M. J. Cowley, V. Huch, and D. Scheschkewitz*, Organometallics, 2013, 32, 1591–4.
Reversible base coordination to a disilene K. Leszczyńska, K. Abersfelder, A. Mix, B. Neumann, H.-G. Stammler, M. J. Cowley, P. Jutzi, and D. Scheschkewitz*, Angew. Chem. Int. Ed., 2012, 51, 6785–8.
Transmetallation reactions of a lithium disilenide M. J. Cowley, K. Abersfelder, A. J. P. White, M. Majumdar, and D. Scheschkewitz*, Chem. Commun., 2012, 48, 6595–7.
Phosphide Delivery to a Cyclotrisilene T. P. Robinson, M. J. Cowley, D. Scheschkewitz*, and J. M. Goicoechea*, Angew. Chem. Int. Ed., 2015, 54, 683–86.
From Disilene (Si=Si) to Phosphasilene (Si=P) and Phosphacumulene (P=C=N) P. Willmes, M. J. Cowley, M. Hartmann, M. Zimmer, V. Huch, and D. Scheschkewitz*, Angew. Chem. Int. Ed., 2014, 53, 2216–20.
Donor–Acceptor Adducts of a 1, 3‐Disila‐2‐oxyallyl Zwitterion M. J. Cowley, V. Huch, and D. Scheschkewitz*, Chem. Eur. J., 2014, 20, 9221–24.
Carbonylation of Cyclotrisilenes M. J. Cowley, Y. Ohmori, V. Huch, M. Ichinohe, A. Sekiguchi, and D. Scheschkewitz*, Angew. Chem. Int. Ed., 2013, 52, 13247–50. (‘Very Important Paper’)
Equilibrium between a cyclotrisilene and an isolable base adduct of a disilenyl silylene M. J. Cowley, V. Huch, H. S. Rzepa, and D. Scheschkewitz*, Nature Chem., 2013, 5, 876–9.
Functionalized cyclic disilenes via ring expansion of cyclotrisilenes with isocyanides Y. Ohmori, M. Ichinohe, A. Sekiguchi, M. J. Cowley, V. Huch, and D. Scheschkewitz*, Organometallics, 2013, 32, 1591–4.
Reversible base coordination to a disilene K. Leszczyńska, K. Abersfelder, A. Mix, B. Neumann, H.-G. Stammler, M. J. Cowley, P. Jutzi, and D. Scheschkewitz*, Angew. Chem. Int. Ed., 2012, 51, 6785–8.
Transmetallation reactions of a lithium disilenide M. J. Cowley, K. Abersfelder, A. J. P. White, M. Majumdar, and D. Scheschkewitz*, Chem. Commun., 2012, 48, 6595–7.
From postdoctoral work at University of York
Probing signal amplification by reversible exchange using an NMR flow system R. E. Mewis, K. D. Atkinson, M. J. Cowley, S. B. Duckett*, G. G. R. Green,* R. A Green, L. R. Highton, D. Kilgour, L. S. Lloyd, J. a B. Lohman, and D. C. Williamson, Magn. Reson. Chem., 2014 doi: 10.1002/mrc.4073.
Hyperpolarisation through reversible interactions with para-hydrogen L. S. Lloyd, A. Asghar, M. J. Burns, A. Charlton, S. Coombes, M. J. Cowley, G. J. Dear, S. B. Duckett,* G. R. Genov, G. G. R. Green,* L. A. R. Highton, A. J. J. Hooper, M. Khan, I. G. Khazal, R. J. Lewis, R. E. Mewis, A. D. Roberts, A. J. Ruddlesden, Catal. Sci. Technol., 2014, 4, 3544–54.
Iridium N-heterocyclic carbene complexes as efficient catalysts for magnetization transfer from para-hydrogen M. J. Cowley, R. W. Adams, K. D. Atkinson, M. C. R. Cockett, S. B. Duckett*, G. G. R. Green*, J. a B. Lohman, R. Kerssebaum, D. Kilgour, and R. E. Mewis, J. Am. Chem. Soc., 2011, 133, 6134–7.
Reversible interactions with para-hydrogen enhance NMR sensitivity by polarization transfer R. W. Adams, J. A. Aguilar, K. D. Atkinson, M. J. Cowley, P. I. P. Elliott, S. B. Duckett*, G. G. R. Green,* I. G. Khazal, J. López-Serrano, and D. C. Williamson, Science, 2009, 323, 1708–11.
Spontaneous Transfer of Para hydrogen Derived Spin Order to Pyridine at Low Magnetic Field Kevin D Atkinson, M. J. Cowley, P. I. Elliott, S. B. Duckett*, G. G. R. Green*, J. López-Serrano, and A. C. Whitwood, J. Am. Chem. Soc., 2009, 131, 13362–8.
Probing signal amplification by reversible exchange using an NMR flow system R. E. Mewis, K. D. Atkinson, M. J. Cowley, S. B. Duckett*, G. G. R. Green,* R. A Green, L. R. Highton, D. Kilgour, L. S. Lloyd, J. a B. Lohman, and D. C. Williamson, Magn. Reson. Chem., 2014 doi: 10.1002/mrc.4073.
Hyperpolarisation through reversible interactions with para-hydrogen L. S. Lloyd, A. Asghar, M. J. Burns, A. Charlton, S. Coombes, M. J. Cowley, G. J. Dear, S. B. Duckett,* G. R. Genov, G. G. R. Green,* L. A. R. Highton, A. J. J. Hooper, M. Khan, I. G. Khazal, R. J. Lewis, R. E. Mewis, A. D. Roberts, A. J. Ruddlesden, Catal. Sci. Technol., 2014, 4, 3544–54.
Iridium N-heterocyclic carbene complexes as efficient catalysts for magnetization transfer from para-hydrogen M. J. Cowley, R. W. Adams, K. D. Atkinson, M. C. R. Cockett, S. B. Duckett*, G. G. R. Green*, J. a B. Lohman, R. Kerssebaum, D. Kilgour, and R. E. Mewis, J. Am. Chem. Soc., 2011, 133, 6134–7.
Reversible interactions with para-hydrogen enhance NMR sensitivity by polarization transfer R. W. Adams, J. A. Aguilar, K. D. Atkinson, M. J. Cowley, P. I. P. Elliott, S. B. Duckett*, G. G. R. Green,* I. G. Khazal, J. López-Serrano, and D. C. Williamson, Science, 2009, 323, 1708–11.
Spontaneous Transfer of Para hydrogen Derived Spin Order to Pyridine at Low Magnetic Field Kevin D Atkinson, M. J. Cowley, P. I. Elliott, S. B. Duckett*, G. G. R. Green*, J. López-Serrano, and A. C. Whitwood, J. Am. Chem. Soc., 2009, 131, 13362–8.
Para-hydrogen induced polarization without incorporation of para-hydrogen into the analyte D. Atkinson, M. J. Cowley, S. B. Duckett*, P. I. Elliott, G. G. Green*, J. López-Serrano, I. G. Khazal, and A. C. Whitwood, Inorg. Chem., 2008, 48, 663–70.
From my PhD at University of York
Rhodium vinylidene and alkyne complexes containing a pendant uracil group M. J. Cowley, J. M. Lynam*, and A. C. Whitwood, J. Organomet. Chem., 2010, 695, 18–25.
Ruthenium alkynyl, carbene and alkenyl complexes containing pendant uracil groups: an investigation into the formation of alkenyl-phosphonio complexes J. Cowley, J. M. Lynam*, R. S. Moneypenny, A. C. Whitwood, and A. J. Wilson, Dalton Trans., 2009, 9529–42.
A mechanistic study into the interconversion of rhodium alkyne, alkynyl hydride and vinylidene complexes Cowley, J. Lynam*, and J. Slattery, Dalton. Trans., 2008, 4552–4. (‘Hot paper’)
One-Electron Reduction of Molybdenum η2 (4e)-Alkyne Complexes as a Pathway to the η2 (3e) Vinyl Ligand S. Baines, M. Cowley, A. Chafen, and J. Lynam*, Organometallics, 2007, 26, 1093–5.
Transition metal vinylidene complexes as supramolecular building blocks: nucleobase-mediated self-assembly of crystals with hexagonal symmetry M. Cowley and J. Lynam*, Dalton. Trans., 2007, 4427–38.
From my PhD at University of York
Rhodium vinylidene and alkyne complexes containing a pendant uracil group M. J. Cowley, J. M. Lynam*, and A. C. Whitwood, J. Organomet. Chem., 2010, 695, 18–25.
Ruthenium alkynyl, carbene and alkenyl complexes containing pendant uracil groups: an investigation into the formation of alkenyl-phosphonio complexes J. Cowley, J. M. Lynam*, R. S. Moneypenny, A. C. Whitwood, and A. J. Wilson, Dalton Trans., 2009, 9529–42.
A mechanistic study into the interconversion of rhodium alkyne, alkynyl hydride and vinylidene complexes Cowley, J. Lynam*, and J. Slattery, Dalton. Trans., 2008, 4552–4. (‘Hot paper’)
One-Electron Reduction of Molybdenum η2 (4e)-Alkyne Complexes as a Pathway to the η2 (3e) Vinyl Ligand S. Baines, M. Cowley, A. Chafen, and J. Lynam*, Organometallics, 2007, 26, 1093–5.
Transition metal vinylidene complexes as supramolecular building blocks: nucleobase-mediated self-assembly of crystals with hexagonal symmetry M. Cowley and J. Lynam*, Dalton. Trans., 2007, 4427–38.